its the orangehead in the 5th spot its "KANO KYOSUKE" from Hungry Heart: Wild Striker"
Called Orangehead jokingly by some of his friends, Kyōsuke learns the tricks and trades of soccer from his illustrious older brother, A.C. Milan playmaker Kanō Seisuke. After Seisuke's departure, he slowly loses interest in the game, but rediscovers his love for it after a fated meeting with Miki. Initially joining as the coach of Jyoyō's girl's soccer team, the determination exhibited by the girls, especially Miki, invigorates his passion for soccer, and soon he joins Jyoyō's male soccer team, emerging as their ace striker. In the last episode, he becomes a player for AFC Ajax
